2-Trimethylsilylthiazole 95.0%(GC)

95.0%(GC)


Linear Formula:  C6H11NSSi
Molecular Weight:  157.31g/mol
CAS Number: 79265-30-8

Properties

Vapour pressure 1.6±0.3 mmHg at 25℃
Water Solubility Insoluble
Assay Purity >95%(GC)
Refractive index n20/D 1.497 (lit.)
B pt. 56-57 ℃/10 mmHg (lit.)
Density 0.985 g/mL at 25 ℃ (lit.)

Safety Information

Hazard Statement(s) H315-H319-H227
Precautionary Statement  P501-P210-P264-P280-P302 + P352-P370 + P378-P337 + P313-P305 + P351 + P338-P362 + P364-P332 + P313-P403 + P235
Symbol
Signal word Warning
HS Code 2934100090
Flash point 57℃
Storage Temp. 0-10℃
Storage Class 3
Packaging Glass Bottle
UN Number 1993

Description

Recommended products
5-Bromo-2-Methoxybenzenesulfonyl Chloride 98%

Application
2-(Trimethylsilyl)thiazole was employed as a formyl anion equivalent.2-(Trimethylsilyl)thiazole may be used in the synthesis of amino pentoses and sphingosines.It may be employed as a formyl anion equivalent for the one-carbon homologation method of protected monosaccharides useful in the synthesis of the rare hexoses.

Purpose
For R&D use onlynot for drug household or other uses.

General Description
2-(Trimethylsilyl)thiazole is useful source of formyl anion for the construction of 12-dihydroxyaldehyde fragments en route to higher carbohydrates.It can be prepared from 2-bromothiazolen-butyllithium and chlorotrimethylsilane. It is useful one-carbon homologating reagent for alkoxy aldehydes amino aldehydes and dialdoses.