4-Ethynylaniline 98.0%(HPLC)


Linear Formula:  C8H7N
Molecular Weight:  117.15g/mol
CAS Number: 14235-81-5

Properties

Vapour pressure 0.0949mmHg at 25℃
Refractive index 1.589
B pt. 223.7℃ at 760 mmHg
M pt. 98-102 ℃(dec.)(lit.)
Density 1.05 g/cm3

Safety Information

Hazard Statement(s) H315 - H319 - H335
Precautionary Statement  P302 + P352 - P305 + P351 + P338
Symbol
Signal word Warning
HS Code 2921420090
Storage Temp. Store at room temperature.
Packaging Glass Bottle

Description

Recommended products
Ethanolamine 98%

Application
4-Ethynylaniline may be used in the synthesis ofN-methyliminodiethyl 4-(4-ethynylphenyliminomethyl)benzeneboronate.[5]It can also be used to prepare an acetylene ligand HC2-NDI (NDI 1458-naphthalenediimide). Used as an alkyne component in a synthesis of indoles from nitroarenes in the presence of a palladium-phenantroline catalyst.

Purpose
For R&D use onlynot for drug household or other uses.

General Description
4-Ethynylaniline also known asp-ethynylaniline is a terminal alkyne. Its synthesis using 2-methyl-3-butyn-2-ol (MEBYNOL) has been reported.[2]The transition metal catalyzed polymerization of 4-ethynylaniline to afford poly(4-ethynylaniline) has been reported.[3]The impact of the surface functionalization with 4-ethynylaniline on the thermal behavior of multi-walled carbon nanotubes (MWNTs) and graphene has been investigated.