Diphenyl-2-Pyridylphosphine 97.0%(GC)

97.0%(GC)


Linear Formula:  C17H14NP
Molecular Weight:  263.273 g/mol
CAS Number: 37943-90-1

Properties

Vapour pressure 0.0±0.8 mmHg at 25℃
Assay Purity >97%(GC)
B pt. 377.5℃ at 760 mmHg
M pt. 85℃

Safety Information

Hazard Statement(s) H315 - H319 - H335 - H413
Precautionary Statement  P273 - P302 + P352 - P305 + P351 + P338
Symbol
Signal word Warning
HS Code 2933399090
Flash point 182.1℃
Storage Temp. Store at cold temperature
Packaging Glass bottle

Description

Recommended products
2-(Diphenylphosphino)pyridine

Application
Ligand for metal-catalyzed carbonylations hydration dehydrogenative coupling carbostannylation distannylation and silylation reagent for Mitsunobu reaction.

Purpose
For R&D use onlynot for drug household or other uses.

General Description
Diphenyl-2-pyridylphosphine is an organophosphorus compound with the formula P(C6H5)2(2-C5H4N). It is the most widely used mono-pyridylphosphine ligand. Other mono-pyridylphosphines ligands (3- 4-) are not common in chemical literature however tris-pyridylphosphines have been thoroughly investigated as ligands in transition metal complexes used for catalysis. Pyridylphosphines including diphenyl-2-pyridylphosphine may bind transition metals as monodentate or bidentate ligands4. Diphenyl-2-pyridylphosphine behaves as a P-bound monodentate ligand or a PN-bound bidentate ligand. Diphenyl-2-pyridylphosphine is a sought after ligand for its ability to relay protons to transition metals such as palladium(II) in homogeneous catalysis.