Diphenyl-2-Pyridylphosphine 97.0%(GC)
97.0%(GC)
Synonym: 2-(Diphenylphosphino)pyridine
Linear Formula:
C17H14NP
Molecular Weight: 263.273 g/mol
CAS Number: 37943-90-1
Properties
| Vapour pressure | 0.0±0.8 mmHg at 25℃ |
| Assay Purity | >97%(GC) |
| B pt. | 377.5℃ at 760 mmHg |
| M pt. | 85℃ |
Safety Information
| Hazard Statement(s) | H315 - H319 - H335 - H413 |
| Precautionary Statement | P273 - P302 + P352 - P305 + P351 + P338 |
| Symbol |
|
| Signal word | Warning |
| HS Code | 2933399090 |
| Flash point | 182.1℃ |
| Storage Temp. | Store at cold temperature |
| Packaging | Glass bottle |
Description
Recommended products
2-(Diphenylphosphino)pyridine
Application
Ligand for metal-catalyzed carbonylations hydration dehydrogenative coupling carbostannylation distannylation and silylation reagent for Mitsunobu reaction.
Purpose
For R&D use onlynot for drug household or other uses.
General Description
Diphenyl-2-pyridylphosphine is an organophosphorus compound with the formula P(C6H5)2(2-C5H4N). It is the most widely used mono-pyridylphosphine ligand. Other mono-pyridylphosphines ligands (3- 4-) are not common in chemical literature however tris-pyridylphosphines have been thoroughly investigated as ligands in transition metal complexes used for catalysis. Pyridylphosphines including diphenyl-2-pyridylphosphine may bind transition metals as monodentate or bidentate ligands4. Diphenyl-2-pyridylphosphine behaves as a P-bound monodentate ligand or a PN-bound bidentate ligand. Diphenyl-2-pyridylphosphine is a sought after ligand for its ability to relay protons to transition metals such as palladium(II) in homogeneous catalysis.
Documents
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